Intro to Chemical Reactions

Chemical change is a central concept in chemistry. The goal of chemists is to know how and why a substance changes in the presence of another substance or even by itself. Because there are tens of millions of known substances, there are a huge number of possible chemical reactions. In this chapter, we will find that many of these reactions can be classified into a small number of categories according to certain shared characteristics.
In science, a law is a general statement that explains a large number of observations. Before being accepted, a law must be verified many times under many conditions. Laws are therefore considered the highest form of scientific knowledge and are generally thought to be inviolable. Scientific laws form the core of scientific knowledge. One scientific law that provides the foundation for understanding in chemistry is the law of conservation of matter. It states that in any given system that is closed to the transfer of matter (in and out), the amount of matter in the system stays constant. A concise way of expressing this law is to say that the amount of matter in a system is conserved.

Law of Conservation of Mass

According to this law, during any physical or chemical change, the total mass of the products remains equal to the total mass of the reactants.
100 g of mercuric oxide reacts to form 92.6 g of mercury and 7.4 g of oxygen. The total mass of the reactant (mercuric oxide, 100g) is equal to the total mass of products (92.6 g of mercury + 7.4 g of oxygen = 100g of products).
Another way of stating this is, “In a chemical reaction, matter is neither created nor destroyed.” The law of conservation of mass is also known as the “law of indestructibility of matter.”
What does this mean for chemistry? In any chemical change, one or more initial substances change into a different substance or substances. Both the initial and final substances are composed of atoms because all matter is composed of atoms. According to the law of conservation of matter, matter is neither created nor destroyed, so we must have the same number and kind of atoms after the chemical change as were present before the chemical change.
For example, it may seem as though burning destroys matter, but the same amount, or mass, of matter still exists after a campfire as before. The figure below shows that when wood burns, it combines with oxygen and changes not only to ashes, but also to carbon dioxide and water vapor. The gases float off into the air, leaving behind just the ashes. Suppose we had measured the mass of the wood before it burned and the mass of the ashes after it burned. Also suppose we had been able to measure the oxygen used by the fire and the gases produced by the fire. What would we find? The total mass of matter after the fire would be the same as the total mass of matter before the fire.
A picture of fire burning, followed by an arrow pointing from the fire to a pile of ashes leftover from a campfire. The arrow represents a chemical change.
Burning is a chemical process. The flames are caused as a result of a fuel undergoing combustion (burning). Images used with permission (CC BY-SA 2.5; Einar Helland Berger for fire and for ash).


This page is based on “Chemistry 2e” by Paul Flowers, Klaus Theopold, Richard Langley, William R. Robinson, PhDOpenstax which is licensed under CC BY 4.0. Access for free at

This page is based on “The Basics of General, Organic, and Biological Chemistry” by David W Ball, John W Hill, Rhonda J ScottSaylor which is licensed under CC BY-NC-SA 4.0. Access for free at


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