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35 Ferrite

Optical micrograph of ferrite microstructure
Optical micrograph of a full ferrite microstructure by García de Andrés, Carlos.

Ferrite is one of the allotropic forms of iron. It is also called alpha iron. Below 912 °C (1,674 °F), iron has a body-centered cubic (bcc) crystal structure.

3D depiction of atomic structure of body centered cubic.
Body centered cubic unit cell CC0

It is thermodynamically stable and a fairly soft metal.

The primary phase of low-carbon or mild steel and most cast irons at room temperature is magnetic and referred to as ferromagnetic in materials science.

Shows how circles pack together to make efficient use of space and the empty spaces created around the circles.
Packed circles of simple cubic and hexagonal shapes. The interstitial sites are the voids in the structures where the circles do not contact one another. CC BY-SA 4.0

It has a hardness of approximately 80 Brinell. The maximum solubility of carbon is about 0.02 wt% at 1,341 °F (727 °C). When it dissolves in iron, carbon atoms occupy interstitial “holes”.  The carbon introduces a strong local strain field.

Mild steel (carbon steel with up to about 0.2 wt% C) consists mostly of ferrite and increasing amounts of cementite (Fe3C, an iron carbide). The mixture adopts a lamellar structure called pearlite. Since bainite and pearlite each contain ferrite as a component, any iron-carbon alloy will contain some amount of ferrite if it is allowed to reach equilibrium at room temperature. The amount of ferrite depends on the cooling process.

 

 


Derived from Allotropes of iron – Wikipedia accessed and available online 5 December 2024.

Ferrite image: Caballero, Francisca & Capdevila, Carlos & García de Andrés, Carlos. (2001). Modelling of kinetics of austenite formation in steels with different initial microstructures. Isij International. 41. 1093-1102.

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Metallurgy Copyright © 2024 by Lisa Hillyard is licensed under a Creative Commons Attribution 4.0 International License, except where otherwise noted.