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44 Annealing

Annealing is the process for making material softer while producing uniform material properties. A material can be annealed by heating it to a specific temperature and then letting it slowly cool down inside an oven. This process is expensive because the oven is unusable during the cool down process.

In metallurgy, annealing is a heat treatment that alters the physical and sometimes chemical properties of a material to increase its ductility and reduce its hardness, making it more workable. It involves heating a material above its recrystallization temperature, maintaining a suitable temperature for an appropriate amount of time and then cooling.

In annealing, atoms migrate in the crystal lattice and the number of dislocations decreases, leading to a change in ductility and hardness. As the material cools it recrystallizes. For many alloys, including carbon steel, the crystal grain size and phase composition, which ultimately determine the material properties, are dependent on the heating rate and cooling rate. Hot working or cold working after the annealing process alters the metal structure, so further heat treatments may be used to achieve the properties required. With knowledge of the composition and phase diagram, heat treatment can be used to adjust from harder and more brittle to softer and more ductile.

In the case of ferrous metals, such as steel, annealing is performed by heating the material (generally until glowing) for a while and then slowly letting it cool to room temperature in still air. Copper, silver and brass can be either cooled slowly in air, or quickly by quenching in water.  In this fashion, the metal is softened and prepared for further work such as shaping, stamping, or forming.

Image of metal going into hot oven.
Metal going into a hot oven. Source: The Virtual Machine Shop (2011) CC BY-SA 4.0
Image of metal heating up in oven
Metal inside an oven heating up Source: The Virtual Machine Shop (2011) CC BY-SA 4.0
Image of cooled metal removed from cool oven
Metal withdrawn from a cool oven. Source: The Virtual Machine Shop (2011) CC BY-SA 4.0

 

Thought Experiment:

The lecturer mentions that annealing is used to soften metal that has been work hardened. Isolate the concept of work hardening for a minute as there are many reasons to anneal metal and not all of them have to do with relieving stresses induced by work hardening.

Videos

Watch this 5:52 video Annealing Metal by AlbertaUArts. (2016)

Watch this 8:09 video Detailed Explanation of Annealing Heat Treatment | Process, Furnace, Stages, Types, etc by James Sword Engineering (2024)

Process Annealing

Process annealing, also called intermediate annealingsubcritical annealing, or in-process annealing, is a heat treatment cycle that restores some of the ductility to a product being cold-worked so it can be cold-worked further without breaking.

The temperature range for process annealing ranges from 260 °C (500 °F) to 760 °C (1400 °F), depending on the alloy in question. This process is mainly suited for low-carbon steel. The material is heated up to a temperature just below the lower critical temperature of steel. Cold-worked steel normally tends to possess increased hardness and decreased ductility, making it difficult to work. Process annealing tends to improve these characteristics. This is mainly carried out on cold-rolled steel like wire-drawn steel, centrifugally cast ductile iron pipe etc.

Full Annealing

A full annealing typically results in the second most ductile state a metal can assume for metal alloy. Its purpose is to originate a uniform and stable microstructure that most closely resembles the metal’s phase diagram equilibrium microstructure, thus letting the metal attain relatively low levels of hardness, yield strength and ultimate strength with high plasticity and toughness. To perform a full, anneal on a steel for example, steel is heated to slightly above the austenitic temperature and held for sufficient time to allow the material to fully form austenite or austenite-cementite grain structure. The material is then allowed to cool very slowly so that the equilibrium microstructure is obtained. In most cases this means the material is allowed to furnace cool (the furnace is turned off and the steel is let cool down inside) but in some cases it is air cooled. The cooling rate of the steel has to be sufficiently slow so as to not let the austenite transform into bainite or martensite, but rather have it completely transform to pearlite and ferrite or cementite. This means that steels that are very hardenable (i.e. tend to form martensite under moderately low cooling rates) have to be furnace cooled. The details of the process depend on the type of metal and the precise alloy involved. In any case the result is a more ductile material but a lower yield strength and a lower tensile strength. This process is also called LP annealing for lamellar pearlite in the steel industry as opposed to a process anneal, which does not specify a microstructure and only has the goal of softening the material. Often the material to be machined is annealed, and then subject to further heat treatment to achieve the final desired properties.

 


Derived from Annealing (materials science) – Wikipedia accessed and available 11 December 2024 and The Virtual Machine Shop via the WayBack Machine Heat Treating – Annealing (2011) accessed and available 17 January 2024.

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Metallurgy Copyright © 2024 by Lisa Hillyard is licensed under a Creative Commons Attribution 4.0 International License, except where otherwise noted.